3. A Wilkinson’s catalyst is widely used in the hydrogenation of alkenes. Show a catalytic cycle, including: i. chemical structure of the catalyst, with complete stereochemistry ii. molecular geometry of catalyst iii. type of reactions involved iv. the appropriate starting material, reagent and solvent v. major and minor end-products vi. all intermediates, for each reaction stated in (iii)
We can see here that the catalytic cycle for the hydrogenation of alkenes using Wilkinson's catalyst involves several steps.
What are the steps involved?Here's an overview of the catalytic cycle, including the necessary details:
i. Chemical structure of the catalyst:
Wilkinson's catalyst, also known as chloridotris(triphenylphosphine)rhodium(I), has the following chemical structure: [RhCl(PPh3)3]
ii. Molecular geometry of the catalyst:
The Wilkinson's catalyst has a trigonal bipyramidal geometry around the rhodium center. The three triphenylphosphine (PPh3) ligands occupy equatorial positions, while the chloride (Cl) ligand occupies an axial position.
iii. Type of reactions involved:
The catalytic cycle involves several reactions, including:
Oxidative addition: The rhodium center undergoes oxidative addition, reacting with molecular hydrogen (H2) to form a dihydride intermediate.Alkene coordination: The alkene substrate coordinates to the rhodium center, forming a π-complex.Hydrogenation: The coordinated alkene undergoes hydrogenation, resulting in the addition of hydrogen atoms to the double bond and formation of a metal-alkyl intermediate.Reoxidation: The metal-alkyl intermediate reacts with a hydrogen molecule to regenerate the rhodium dihydride species.iv. Starting material, reagent, and solvent:
The starting material is an alkene, and the reagent is Wilkinson's catalyst ([RhCl(PPh3)3]). The reaction is typically carried out in a suitable solvent, such as dichloromethane (CH2Cl2) or tetrahydrofuran (THF).
v. Major and minor end-products:
The major end-product of the hydrogenation reaction is the fully saturated alkane, resulting from the addition of hydrogen across the double bond. The minor end-product may include cis- or trans-configured alkanes if the original alkene substrate possesses geometric isomers.
vi. Intermediates:
The intermediates in the catalytic cycle include:
Rhodium dihydride complex: [RhH2(PPh3)3]Alkene-Rhodium π-complex: [Rh(η2-alkene)(PPh3)3]Metal-alkyl intermediate: [Rh(alkyl)(PPh3)3]These intermediates play a crucial role in facilitating the hydrogenation reaction and enabling the catalytic cycle to proceed.
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22.4 L is the volume of any gas regardless of atmospheric conditions.
O True
O False
X-ray crystallography is a technique that allows scientists to determine the
ionic and atomic radii of elements. Which of these statements correctly
describes a trend in ionic or atomic radii in the periodic table?
Atomic radii decreases along a period and increases along a group in the periodic table.
What is periodic table?
Periodic table is a tabular arrangement of elements in the form of a table. In the periodic table, elements are arranged according to the modern periodic law which states that the properties of elements are a periodic function of their atomic numbers.
It is called as periodic because properties repeat after regular intervals of atomic numbers . It is a tabular arrangement consisting of seven horizontal rows called periods and eighteen vertical columns called groups.
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A chemistry student collected 0.032l of H2 gas at 1.1 atm pressure and 24C, using the following chemical reaction. How many grams of magnesium must have reacted?
Mg (s) + HCl 9 (aq) becomes H2 9g) + MgCl2 (aq)
We need more information to solve this problem. Specifically, we need to know the volume (or concentration) of HCl used to react with the Mg. Without that information, we cannot determine how many grams of Mg reacted.
How can a chemical equation be balanced? Responses by using exponents to adjust the number of atoms of each element so that the products have the same number of atoms of the same element as in the reactants by using exponents to adjust the number of atoms of each element so that the products have the same number of atoms of the same element as in the reactants by using new elements to adjust the number of atoms of each element so that the products have the same number of atoms of the same element as in the reactants by using new elements to adjust the number of atoms of each element so that the products have the same number of atoms of the same element as in the reactants by using subscripts to adjust the number of atoms of each element so that the products have the same number of atoms of the same element as in the reactants by using subscripts to adjust the number of atoms of each element so that the products have the same number of atoms of the same element as in the reactants by using coefficients to adjust the number of atoms of each element so that the products have the same number of atoms of the same element as in the reactants
The balancing of chemical equations is based on the law of conservation of mass.
How could a chemical process be made to balance out? Which integers can be changed, and which cannot?
When an equation is balanced, the coefficients can only be changed (the numbers in front of molecules or atoms).
The coefficients are indicated by the numerals in front of the molecule. Subscripts are the smaller numerals found following atoms. These cannot be changed while balancing chemical equations!
How is a chemical equation brought to equilibrium?
the algebraic balancing technique. Chemical equations can be balanced by assigning algebraic variables as stoichiometric coefficients to each species in the unbalanced chemical equation.
Equations in mathematics are used to calculate the values of each of these variables
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Calculate the theoretical yield in moles of magnesium chloride when 37 grams of Mg(s) react with 38 grams of HCl(aq).Write the answer using 2 decimal places and do not use scientific notation.
Answer:
The correct answer is 0.52 moles.
Explanation:
Based on the given question, 37 grams of magnesium reacts with 38 grams of HCl to produce MgCl2 or magnesium chloride. The reaction is:
Mg (s) + 2HCl (aq) ⇒ MgCl2 (aq) + H2 (g)
There is a need to find the theoretical yield in moles of MgCl2. The formula for calculating the no. or moles is mass/molar mass. Therefore, moles of magnesium is 37/24 = 1.54 and moles of HCl will be 38/36.5 = 1.04.
From the reaction it is clear that one mole of magnesium reacts with two moles of HCl, as lesser quantity of HCl is present in the given case, therefore, HCl will be the limiting reagent.
Now theoretical moles of magnesium chloride will be,
= moles of HCl / 2
= 1.04 / 2
= 0.52 moles
Which statement is true about the effect of human activity on atmospheric carbon dioxide?
Responses
Human activity has converted carbon dioxide in the atmosphere to other compounds.
Human activity has added carbon dioxide to the atmosphere.
Human activity consumes carbon dioxide in the atmosphere.
Human activity has disrupted the carbon cycle by preventing it from reaching the atmosphere.
The statement that is true about the effect of human activity on atmospheric carbon dioxide is Human activity has added carbon dioxide to the atmosphere.
Human activities, such as burning fossil fuels (coal, oil, and natural gas) for energy, deforestation, and industrial processes, have significantly increased the concentration of carbon dioxide in the Earth's atmosphere.
These activities release carbon dioxide that was previously stored in long-term reservoirs, such as fossil fuels and forests, into the atmosphere. This additional carbon dioxide contributes to the greenhouse effect and is a major driver of anthropogenic climate change.
The other statements mentioned are not accurate:
Human activity does not convert carbon dioxide in the atmosphere to other compounds on a large scale. There may be certain localized processes or technologies that aim to capture and convert carbon dioxide, but they are not widespread enough to significantly impact the overall levels of atmospheric carbon dioxide.
Human activity does not consume carbon dioxide in the atmosphere. In fact, human activities release carbon dioxide into the atmosphere through various processes, as mentioned above.
Human activity does not disrupt the carbon cycle by preventing it from reaching the atmosphere. The carbon cycle involves the movement of carbon between the atmosphere, oceans, land, and living organisms.
While human activities can impact the carbon cycle through land-use changes and deforestation, the overall effect is an increase in atmospheric carbon dioxide levels rather than preventing carbon dioxide from reaching the atmosphere.
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What are the concentrations of HSO, SO and H+ in a 0.20 M KHSO4 solution?
The concentration of the solution is as follows;
H⁺ = 0.045 M
SO₄(²⁻) = 0.045 M
HSO₄⁻ = 0.155 M
How do we solve for the concentration of HSO, SO and H+?Potassium hydrogen sulfate, KHSO₄ is a salt that will completely dissociate in water into its constituent ions, K+ and HSO₄⁻.
HSO₄⁻ ⇌ H⁺ + SO₄(²⁻)
Let's say x is the amount of HSO4- that dissociates. Then it will be
HSO₄⁻ = 0.20 - x
H⁺ = x
SO₄(²⁻) = x
Now, we can use the Ka for HSO4-, which is given as 1.3 x 10⁻². We will get the equation
Ka = (H⁺)(SO₄(²⁻)) / (HSO₄⁻ )
Substituting the expressions for the equilibrium concentrations gives:
1.3 x 10⁻² = (x)(x) / (0.20 - x)
So the concentrations are:
HSO₄⁻ = 0.20 - x = 0.20 - 0.045 = 0.155 M
H⁺ = x = 0.045 M
SO₄(²⁻) = x = 0.045 M
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The force of gravity from Earth to Mars is___
a. less than the force of gravity from Mars to Earth.
b. equal to the force of gravity from Mars to Earth.
less than the force of gravity from mars to earth
Which of the following is NOT a
physical property?
A melting point
B state of matter
C density
D flammability
are the answers correct?
All the answers to the given reactions are correct.
What are Reactions?A chemical reaction is a process of converting the reactants into products that have different chemical properties. The substances initially involved in the reactions are called Reactants. The final substance which is formed when reactants undergo chemical change is known as the Product.
Chemical reactions happen at specific reaction rates at given temperatures and given conditions. Different reactions are classified as redox reactions in which oxidation and reduction take place or non-redox reactions where no oxidation or reduction takes place.
Given:
In Reaction 1, the Benzene ring undergoes Fridel Crafts alkylation, followed by Clemensen's reduction which yields Propylbenzene.
In Reaction 2, the Benzene ring undergoes Friedel Crafts alkylation which gives tertiary butyl benzene.
In Reaction 3, benzoic acid reacts with LiOH yielding the product.
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Electrolysis Is One of the Modern Technologies in Architecture’ Prepare an Investigatory Report That Supports the Statement”.
Electrolysis is a technique that separates natural elements. It is commercially used to obtain important materials (e.g., pure metals) for construction.
Electrolysis refers to the use of an electric current to trigger non-spontaneous chemical reactions.
This technology (electrolysis) is commercially important in industry, construction and therefore also in architecture in order to extract metals and minerals from the ground.
Electrolysis uses particular electrolytic cells in order to extract highly pure metals from ores.
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Answer: Electrolysis is a technique that separates natural elements. It is commercially used to obtain important materials (e.g., pure metals) for construction.
Electrolysis refers to the use of an electric current to trigger non-spontaneous chemical reactions.
This technology (electrolysis) is commercially important in industry, construction and therefore also in architecture in order to extract metals and minerals from the ground.
Electrolysis uses particular electrolytic cells in order to extract highly pure metals from ores.
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Please help i need this chart filled out!!!
The volume of the solids are found in the attached table.
What are the unit for measuring volume of liquids?Volume of a substance refers to the amount of space a given mass of the substance occupies.
Since liquids have no definite volume, the volume of liquids are measured using containers.
Also, the volume of solids can be determined by displacing liquids.
The unit for measuring the volume of a liquid substance is liters.
Other multiples of the base unit are, mL, cL, dL, daL, hL, kL.
Considering the given volume of substances, the table can be filled as seen in the attachment.
In conclusion, the volume of solids was determined by displacing liquids water.
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In each of the following reactions identify an acid (if there is one) and then specify whether it is
an acid according to the Arrhenius definitions or the Bronsted-Lowry definitions or both.
a) H2CO3 + CN- HCN + HCO3-
b) F- + HSO4- HF + SO42-
c) HSO4- + H2O H3O+ + SO42-
a) In the reaction \(H_2CO_3 + CN^- = HCN + HCO^{3-}\), \(H_2CO_3\) acts as an acid by donating a proton (\(H^+\)) to \(CN^-\).
b) In the reaction \(F^- + HSO_4^{-} = HF + SO_4^{2-}\), \(HSO_4^{-}\) acts as an acid by donating a proton (\(H^+\)) to \(F^-\).
c) In the reaction \(HSO_4^- + H_2O = H_3O^+ + SO_4^{2-\), \(HSO_4^{-}\) acts as an acid by donating a proton (\(H^+\)) to \(H_2O\).
a) The acid is both an Arrhenius acid (produces \(H^+\) ions in water) and a Bronsted-Lowry acid (donates a proton to a base).
b) The acid is both an Arrhenius acid (produces \(H^+\) ions in water) and a Bronsted-Lowry acid (donates a proton to a base).
c) The acid is a Bronsted-Lowry acid (donates a proton to a base) but not an Arrhenius acid because it does not produce \(H^+\) ions in water. However, the \(H_3O^+\) ion that is formed can be considered an Arrhenius acid because it produces \(H^+\) ions in water.
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What is the pressure, in atmospheres, exerted by a 0.100 mol sample of oxygen in a 2.00 L container at 273 °C? A) 4.48 x 10¹¹ atm B) 2.24 x 10⁰ atm C) 1.12 x 10³ atm D) 2.24 x 10³ atm
The pressure, in atmospheres, exerted by a 0.100 mol sample of oxygen in a 2.00 L container at 273 °C is 2.24 × 10⁰ atm.
How to calculate pressure?The pressure of a substance can be calculated using the following formula;
PV = nRT
P = pressureV = volumen = no of molesR = gas law constantT = temperatureAccording to this question, the pressure, in atmospheres, exerted by a 0.100 mol sample of oxygen in a 2.00 L container at 273 °C can be calculated as follows:
P × 2 = 0.1 × 0.0821 × 546
2P = 4.48266
P = 2.24 × 10⁰ atm
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Why is subatomic particles not made up of atoms
The atom itself is not the smallest known particle, but instead each atom is made up of three individual parts: electrons, protons and neutrons. Furthermore, protons and neutrons themselves are made up of even smaller parts called quarks.
Atoms are not considered the smallest particles of an element upon recent deliberations. An element has to be an atom, because individual protons, neutrons and electrons aren't elements.
Tapeworm and Roundworn
Answer:
Tapeworms and roundworms both belong to the same phylum however, their families are different from one another.
Tapeworms are flat, segmented intestinal parasites of the cat and dog and humans sometimes. They are present in the intestines of pets and depend on them, therefore, are parasites. These parasites look like tape which gives it its name.
Roundworms can also infect humans and the most common cases are among children. When not treated immediately, they can cause severe damage to a human host and can even cause blindness. Tapeworms are white in color with a long, segmented body.
What volume of 0.555M KNO3 solution would contain 12.5 g of solute
The volume of 0.555M KNO3 solution would contain 12.5 g of solute iss 223 mL.
What is the relationship between mass of solute and concentration of solution?The mass of solute in a given volume of solution is related by the formula below:
Molarity = mass/(molar mass * volume)Therefore, volume of solution is given by:
Volume = Mass /molarity * molar mass
Molar mass of KNO₃ = 101 g/mol
Volume = 12.5/(0.555 * 101)
Volume = 0.223 L or 223 mL
In conclusion, the volume of the solution is obtained from the molarity of solution as well as mass and molar mass of solute.
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Which of the following is an incorrect representation for a neutral atom?
36Li
613C
3063Cu
1530P
This representation suggests that the element is phosphorus (P) with a mass number of 30, which is incorrect. The correct mass number for phosphorus is approximately 30.97. The incorrect representation for a neutral atom is 36Li
To determine the correct representation for a neutral atom, we need to consider the atomic number (Z) and mass number (A) of the element. The atomic number represents the number of protons in the nucleus, while the mass number represents the sum of protons and neutrons.
Let's analyze the given representations:
36Li:
This representation suggests that the element is lithium (Li) with a mass number of 36, which is incorrect. The correct mass number for lithium is approximately 6.94.
613C:
This representation suggests that the element is carbon (C) with a mass number of 13, which is correct. Carbon has different isotopes, and 13C represents one of its stable isotopes.
3063Cu:
This representation suggests that the element is copper (Cu) with a mass number of 63, which is correct. Copper has different isotopes, and 63Cu represents one of its stable isotopes.
1530P:
This representation suggests that the element is phosphorus (P) with a mass number of 30, which is incorrect. The correct mass number for phosphorus is approximately 30.97.
Therefore, the incorrect representation for a neutral atom is 36Li, as it does not match the known properties of lithium.
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A reaction that is used to make ClO2 is:HCl + NaOCl +2NaClO2 2ClO2 + 2NaCl + NaOHa) Which element is oxidized? b) Which element is reduced? c) Which substance is the oxidizing agent and which is the reducing agent?
Given the following reaction:
\(\text{HCl + NaOCl + 2NaClO}_2\text{ }\rightarrow2ClO_2\text{ + 2NaCl + NaOH}\)We want to know the element oxidized, the element reduced and the substance that is the oxidizing agent and a reducing agent.
Answer:
a) Element Oxidized = Na
b) Element reduced = Cl
c) NaClO is an oxidizing agent and HCl is a reducing agent.
How do ionic bonds differ from covalent bonds?
if I put elephant toothpaste in a back yard what would happen? I need help on this pls!!! also if you answered this ty!!
Answer:
the elephant toothpaste would go everywhere
How many electron shells/orbitals will be around the nucleus of an atom of aluminum?
A. 1
B. 2
C. 3
4. 4
The number of electrons is revealed by the atomic number. This indicates that an aluminum atom contains 13 electrons. Eight electrons make up shell 1, eight electrons make up shell 2, and three electrons make up shell 3. The correct option is C.
Each subsequent shell that surrounds the nucleus of an atom's electrons is placed farther away from the nucleus. Atomic orbitals make up one or more of the one or more subshells that make up an electron shell.
The first two electrons in aluminum fall into the 1s orbital, followed by the next two electrons into the 2s orbital. The following six electrons complete the second shell's 2p orbital. The 3s orbital is then filled by electrons 11 and 12. The 3p orbital is now occupied by the final electron.
Thus the correct option is C.
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What percentage is the smell from monomer on the Paper towel
Answer: It is the radiation of energy.
Explanation:
10. When dissolved in water, most Group 1 metal salts can be described as
strong electrolytes.
strong acids.
weak electrolytes.
A
B
C
D
non-electrolytes.
(1)
When dissolved in water, most Group 1 metal salts can be described as strong electrolytes.
When Group 1 metal salts are dissolved in water, they can be described as strong electrolytes. This is because Group 1 metals, such as lithium (Li), sodium (Na), potassium (K), and so on, readily lose their outermost valence electron to form positive ions (cations). These cations then dissociate completely in water, separating from the anions to which they were originally bonded.
The dissociation of Group 1 metal salts in water results in the formation of positively charged metal ions and negatively charged non-metal ions (anions). These ions are free to move and conduct electric current, making the solution a good conductor of electricity. The complete dissociation of Group 1 metal salts in water and the presence of freely moving ions make them strong electrolytes.
Strong electrolytes are substances that ionize completely or almost completely in solution, producing a high concentration of ions. This is in contrast to weak electrolytes, which only partially ionize and produce a lower concentration of ions.
In summary, when Group 1 metal salts are dissolved in water, they form strong electrolytes due to their ability to dissociate completely into ions, leading to a high concentration of freely moving ions in the solution, thus enabling efficient electrical conductivity.
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Identify the method used and answer in one word.
a. Pond water is poured through a paper cone _____________
b. Water containing fine sand is allowed to stand for an hour _____________
c. Hot tea turns cold due to this method _____________
d. Water used in injections is prepared by this method _____________
e. Method used at home for killing germs in drinking water
ans soon
Pond water is poured through a paper cone Filtration, Water containing fine sand is allowed to stand for an hour Sedimentation,Hot tea turns cold due to this method Cooling.
What is filtration?Filtration is a process used to separate particles and substances from a mixture or solution. It is commonly used in water treatment, pharmaceutical production, and many other industrial processes. Filtration works by passing the mixture or solution through a porous material or filter medium, which traps the particles and substances while allowing the fluid or air to pass through. Depending on the type of filter used, different sized particles can be filtered out. Some of the most common filtration methods are sedimentation, screening, and centrifugal filtration. Sedimentation involves the settling of particles in a water or other liquid, usually caused by gravity. Screening utilizes a mesh or sieve to separate particles of different sizes.
Pond water is poured through a paper cone Filtration, Water containing fine sand is allowed to stand for an hour Sedimentation,Hot tea turns cold due to this method Cooling,Water used in injections is prepared by this method Distillation,Method used at home for killing germs in drinking water is Boiling.
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Can someone help me please. Use your knowledge of waves and the electromagnetic spectra to explain how electromagnetic radiation affects molecules? Be sure to include 3 specific examples
Why does CO2 have a higher boiling point than CH4 when they both possess dispersion forces?
CO₂ have a higher boiling point than CH₄ when they both possess dispersion forces because CO₂ consists of polar bonds between carbon and oxygen.
Intermolecular forces determine bulk properties, such as the melting points of solids and the boiling points of liquids.
Liquids boil when the molecules have enough thermal energy to overcome the intermolecular attractive forces that hold them together, thereby forming bubbles of vapor within the liquid.
CO₂ have a higher boiling point than CH₄ when they both possess dispersion forces because CO₂ consists of polar bonds between carbon and oxygen. The polarity increases the boiling point of the molecule.
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convert 7.54 x 10^-8 m to nanometers
7.54 *\(10^8\) meters is 75.4 nanometers.
To convert 7.54 * \(10^8\) meters to nanometers, you can multiply the value by \(10^9\)
as, \(10^9\)nanometers = 1 meter.
7.54 * \(10^8\) m * \(10^9\) = 7.54 x \(10^1\) nm
Therefore, 7.54 *\(10^8\) meters is equal to 75.4 nanometers.
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To convert 7.54 x 10^-8 meters to nanometers, you multiply 7.54 x 10^-8 by 1 x 10^9 to get 75.4 nanometers.
Explanation:To convert meters to nanometers, you need to know that 1 meter is equivalent to 1 x 109 nanometers. Therefore, if you were to convert 7.54 x 10-8 m to nanometers, you would multiply 7.54 x 10-8 by 1 x 109.
Here's how you'd do it: 7.54 x 10-8 m * 1 x 109 nm/m = 75.4 nm. So, 7.54 x 10-8 meters is equivalent to 75.4 nanometers.
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‼️‼️‼️need help asap‼️‼️‼️
24. To calculate the molarity of a solution, we must first find out how many moles of \(BaI_2\) are in the solution.
Molar mass of BaI2 = (1 x atomic mass of Ba) + (2 x atomic mass of I)
= (1 x 137.33 g/mol) + (2 x 126.90 g/mol)
= 137.33 g/mol + 253.80 g/mol
= 391.13 g/mol
Number of moles of BaI2 = mass of BaI2 / molar mass of BaI2
= 413 g / 391.13 g/mol
= 1.056 mol
the molarity of the solution using the formula:
Molarity (M) = moles of solute / volume of solution (in liters)
Volume of solution = 750 ml = 750 ml / 1000 ml/L = 0.750 L
Molarity = 1.056 mol / 0.750 L
= 1.408 M
Therefore, the molarity of the solution is 1.408 M.
25. a. \(P_20_7\) - Ionic compound (Phosphorus(V) oxide)
b. \(SnBr_2\) - Ionic compound (Tin(II) bromide)
c. \(Fe(OH)_2\)- Ionic compound (Iron(II) hydroxide)
d. \(Cl_30_8\) - Not a valid chemical formula
26.
A. (NH4)2CO3 is soluble in water (NH4) in an ionic substance called 2CO3 containing the ions carbonate and ammonium.
B. Fe(OH)2 is insoluble in water. Iron(II) hydroxide is only sparingly soluble.
C. CaOH is not soluble in water. Only very little calcium hydroxide is soluble.
D. PbCl2 is insoluble in water. The chloride of lead(II) is sparingly soluble.
27. FeS + 2KCl = FeCl2 + K2S
FeS is an insoluble precipitate.
2KCl dissolves in aqueous solution.
ZnCl2 + SrSO4 = ZnSO4 + SrCl2
SrSO4 is an insoluble precipitate.
ZnCl2 dissolves in aqueous solution.
28. In salt water, the solute is the salt (sodium chloride, or NaCl), and the solvent is water. The element which dissolves in the solvent to form a solution is called solute.
29. Charles's law states that, if the pressure and volume of a gas remain constant, the volume of a gas falls as the temperature increases. As a result, the capacity of the balloon will decrease as it ascends to altitudes where the temperature is -15 °C.
30. The average kinetic energy of the particles of a substance increases with increase in its temperature. This is because temperature is a gauge for the specific kinetic energy of the constituent particles of a substance. On the other hand, the average kinetic energy falls as the temperature increases.
31. When the volume of a gas decreases, its pressure increases. Boyle's law, which states that at a given temperature, the pressure of a gas is inversely proportional to its volume, describes this relationship. On the other hand, pressure falls when volume increases.
32. The pressure of a gas increases along with its temperature. Gay–Lussac's law, which states that the pressure of a gas is directly proportional to its temperature, given the volume and volume of the gas is constant, describes this relationship.
33. The volume of a syringe is reduced as a marshmallow is pressed and the plunger is depressed. As a result the pressure inside the syringe increases. This is because Boyle's law states that the volume and pressure of a gas are inversely proportional. The decrease in volume causes the air inside the syringe to contract, exerting more pressure on the marshmallow, which is then crushed.
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